Physics · 19

Modern Physics

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Problems first

Attempt these before you open a book or a video. Write the argument in the work box and the conclusion in the answer box. Check counts the problem only when both pass, and it does not open the solution. The solution stays locked for twenty minutes after you start the timer.

Attack 1

In the photoelectric effect, why does a brighter light not eject electrons if the frequency is below a threshold?

Timer not started. Twenty minutes of real work before a solution.

Attack 2

State the de Broglie relation and the wavelength of an electron with momentum \(p\).

Timer not started. Twenty minutes of real work before a solution.

Attack 3

For a particle in a one-dimensional infinite well from 0 to \(a\), why are the energies proportional to \(n^2\)?

Timer not started. Twenty minutes of real work before a solution.

Prerequisites

What this actually is

Modern physics on this page is the break with classical mechanics that happens in the first quantum course and the special-relativity chapter that usually sits beside it: photons, de Broglie waves, the Schrödinger equation in one dimension, the infinite well, the harmonic oscillator, tunneling, and the hydrogen atom at the level of its spectrum. Special relativity is the statements you need in order not to lie about simultaneity, time dilation, length contraction, and \(E^2=p^2c^2+m^2c^4\).

This is an entrance, not a graduate quantum course. OpenStax Volume 3 contains the standard modern-physics chapters. MIT 8.04 is the real quantum course and it is the ceiling’s doorway: if you can do its first problem sets, you are past “modern physics” and into quantum mechanics. Griffiths’ Introduction to Quantum Mechanics is the paid book people use next; no edition was verified, so no ISBN is printed. Feynman Volume III is the preview and will not replace 8.04.

A wavefunction is not a smear of the particle. \(|\psi|^2\) is a probability density. Say that sentence correctly or the rest of the page will be mush.

Core results

Statements only. Write the argument before you reveal it. A revealed proof you did not attempt is a paragraph you will not be able to rebuild at 2am.

  1. Photons and relativity, briefly. \(E=hf\), \(p=h/\lambda\) for a photon, and \(E^2=p^2c^2+m^2c^4\) for a particle. Time dilation and length contraction follow from the invariance of the interval.

  2. Schrödinger. \(i\hbar\partial_t\Psi=\hat H\Psi\). For a stationary state, \(\Psi(x,t)=\psi(x)e^{-iEt/\hbar}\) and \(\hat H\psi=E\psi\). \(\int|\Psi|^2=1\). Observables are expectation values.

  3. Infinite well and oscillator. Infinite well energies are \(n^2\pi^2\hbar^2/(2ma^2)\), wavefunctions sines. The harmonic oscillator has \(E_n=\hbar\omega(n+\tfrac12)\), and the ground state is a Gaussian.

  4. Tunneling and hydrogen. A barrier of finite height gives exponential decay inside the barrier and a nonzero transmission probability. The hydrogen spectrum is \(E_n=-13.6\,\mathrm{eV}/n^2\), from the Coulomb Schrödinger equation, with degeneracy you should be able to state.

  5. Spin, stated. Electron spin is a two-state system. The Pauli matrices represent the spin operators in the \(S_z\) basis. A spin measurement along an axis yields \(\pm\hbar/2\).

The ladder

Four rungs, in order. Do not skip a rung because the next one looks more serious.

Tier 0 / First contact

Watch or read once. Do not study from this.

Feynman Lectures, Volume III, from the official site
Read once, do not study from this. Volume III starts from amplitudes. It is a preview of the taste of the subject. 8.04 is the course.

Tier 1 / Main text

The thing you work through.

OpenStax Volume 3, modern physics chapters, then MIT 8.04
OpenStax is the gentle entrance. 8.04 is the real course and becomes the main text as soon as the infinite well feels easy: https://ocw.mit.edu/courses/8-04-quantum-physics-i-spring-2016/

Tier 2 / Hard problems

The problem book.

8.04 problem sets
This is the hard layer. Griffiths is the paid book to buy when you want a second source; no edition was verified.

Tier 3 / The ceiling

The hardest questions that exist at this level.

8.04 exams
The ceiling of this page. A graduate quals in quantum is the next ceiling and is not linked because no specific public exam was verified.

Hardest questions

Names and links. The problem text stays on the source site. Copyrighted contest problems are not copied here. What follows is where they are and why they hurt.

  1. MIT 8.04 problem sets on the infinite well and the harmonic oscillator
    Normalization, orthogonality, and expectation values. The algebra is finite and the mistakes are conceptual.
  2. 8.04 exams
    They mix formalism and a computation. You cannot pattern-match a textbook example.
  3. Photoelectric effect, quantitative, from OpenStax
    The threshold is the whole point. A problem that only asks for \(K_{\max}\) at one frequency is too easy; do one that asks for the stopping potential.
  4. Tunneling transmission for a rectangular barrier, the matching
    Four coefficients, continuity of \(\psi\) and \(\psi'\). The hardness is bookkeeping.
  5. Hydrogen ground-state energy, the variational Gaussian or the exact radial solution
    You should see \(-13.6\,\mathrm{eV}\) come out of a calculation once, not out of a table.

Mastery gate

Pass: derive the infinite-well spectrum, state the photoelectric equation and the reason for the threshold, and complete one early 8.04 problem set. Fail if \(|\psi|^2\) is described as the particle being smeared out, without the word probability.

Diagrams

n = 1, 2
The walls force nodes. The energies go as n squared because k does.

Escalating sets

Five sets. Finish a set before you touch the next. Full sentences, not a circled answer.

Set 1. Light and relativity

  1. Photoelectric equation, and a stopping-potential problem you invent numbers for and solve.
  2. Compton formula, stated, and the classical limit.
  3. Light-clock time dilation.
  4. \(E^2=p^2c^2+m^2c^4\) for a photon, which forces \(E=pc\).
  5. de Broglie wavelength of a 1 eV electron, order of magnitude, with the arithmetic shown.

Set 2. Formalism

  1. Separate the time-dependent Schrödinger equation.
  2. Normalize a sine on \([0,a]\).
  3. Expectation value of \(x\) in the infinite-well ground state.
  4. Show two different infinite-well eigenfunctions are orthogonal.
  5. Probability current, stated.

Set 3. Wells and oscillators

  1. Infinite well spectrum, derived.
  2. A well from \(-a\) to \(a\), even and odd states.
  3. Harmonic oscillator energies, including the zero-point.
  4. Sketch the first three oscillator wavefunctions. Nodes.
  5. A finite well, qualitatively: why the energy is lower than the infinite well of the same width.

Set 4. Beyond one dimension, lightly

  1. Tunneling, the matching conditions.
  2. Hydrogen energies, the formula, and one derivation sketch.
  3. Degeneracy of the hydrogen level \(n\), stated.
  4. Spin: measure \(S_z\) on an \(S_x\) eigenstate. Probabilities.
  5. Pauli matrix \(\sigma_z\), eigenvalues.

Set 5. Ceiling

  1. One 8.04 problem set.
  2. Infinite well from memory.
  3. Photoelectric threshold explanation, oral.
  4. Orthogonality computation.
  5. One exam problem from 8.04 if the set exists on the course site.

Return bank

Ten problems to meet again. Logging a writeup schedules them at 1 day, 7 days, and 30 days in this browser.

  1. Photoelectric threshold.
  2. de Broglie.
  3. Infinite well \(E_n\).
  4. Normalization of the ground state.
  5. Orthogonality of two modes.
  6. Harmonic oscillator zero-point energy.
  7. Light clock.
  8. Tunneling matching.
  9. Hydrogen \(E_n\).
  10. One 8.04 problem you could not start.

Oral pass

Explain the photoelectric threshold, derive the infinite-well energies, and say what \(|\psi|^2\) is. No notes.

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